Efficient alleviation of ultrafiltration membrane fouling in treatment of dye effluent by a novel cationic dendritic starch-based flocculant
简介:Dye effluent has become a challenging problem in wastewater treatment.Ultrafiltration(UF)is a popular method to purify dye effluent,but membrane fouling is a major problem seriously restricting its wide applications.A novel cationic dendritic starch-based flocculant(CL-CS-G)was designed and fabricated.The performance and mechanism of CL-CS-G in alleviation of membrane fouling during the successive flocculation-UF treatment of Acid Green 25 effluent,a typical industrial dye,were evaluated.Compared with polyaluminum chloride(PAC),CL-CS-G showed a lower loss of water flux but a less required dosage,besides,this dendritic flocculant could effectively reduce both reversible and irreversible fouling,and its irreversible fouling resistance was even reduced by 91.2%,because of its distinct structural feature.The hyperbranched structure of CL-CS-G,with relatively loose and net-like configuration but also abundant reactive end-groups contained,caused higher bridging and sweeping flocculation effects in addition to charge neutralization;moreover,produced larger but looser dye flocs,than PAC and its linear analogue,resulting in a looser and porous cake layer,more easily cleaned up,and thus a higher efficiency in alleviation of membrane fouling.The high performance of CL-CS-G in flocculation and alleviation of membrane fouling was confirmed by its high economical efficiency,good reusability of the treated membrane,and effective purification of two other dye effluents and a simulated real dye mixture.CL-CS-G is an efficient,low cost and environmental-friendly flocculant,and thus has high application potentials in pretreatment of dye effluents and alleviation of membrane fouling.展开
学者:YUYANGWangWenxiaoRenHUYang
关键词:Membrane fouling controlFlocculation pretreatmentDye effluentDendritic starch-based flocculantAlleviation performance and mechanisms
在线出版日期:2026-05-11 (网站首发日期)